How to use ammonium nitrate in the garden

Ammonium nitrate: properties of fertilizer

Main properties of ammonium nitrate:

  1. high efficiency of the drug - its consumption per 1 hectare of garden area is no more than 1 kg;
  2. if an excessive amount of lime was added to the soil, this saltpeter will acidify the soil;
  3. the substance dissolves perfectly in water without forming sediment;
  4. Ammonium nitrate contains nitrogen in two forms - with a rapid dissolution period and an extended one;
  5. the temperature characteristics of the soil do not affect the absorption of nitrogen by the root system of plants, so this preparation can be applied immediately after the snow melts;
  6. Almost all applied fertilizer is absorbed by the plant, its losses in the soil are minimal, so it does not need to be embedded into the soil to a depth.

Description of fertilizer - video

In addition, the cost of ammonium nitrate is not too high compared to most fertilizers, which makes the drug very attractive to farmers.

But you should remember some of the disadvantages of this drug:

  1. it cannot be used as a foliar fertilizer, since the ammonium nitrate solution severely burns the foliage even in a small concentration;
  2. This fertilizer cannot be applied to acidic soil;
  3. Failure to comply with the dosage and exceeding it lead to burns of the root system; fertilizing should be done after watering or rain.

Photo of ammonium nitrate - what the fertilizer looks like

Fertilizing should be applied according to the schedule - for most vegetable plants, a single application of ammonium nitrate per season is sufficient

. Instead, you need to add drugs containing potassium and phosphorus.

Ammonium nitrate is a very strong fertilizer; exceeding its dosage when applied to the soil can lead to an increase in the amount of nitrates in fruits

. However, nitrates can be washed out of the soil by heavy watering or during rainy periods.

Application against plant diseases

Why is ammonium nitrate so widespread in industrial farming? It not only nourishes the soil with essential macroelements, but also protects plants from a host of diseases , strengthening their immunity.

This property is especially important when there is intensive exploitation of the land or when crops from the same class are grown annually on one plot (non-compliance with crop rotation). For example, many gardeners allocate the same piece of land for potatoes in small summer cottages every year. And then they wonder why the tubers still in the soil begin to rot. Many people are familiar with this problem - you dig up a seemingly healthy bush, but the potatoes are half rotten and smell bad.

Long-term continuous cultivation of this crop in one place leads to the accumulation of pathogenic fungi in huge quantities in the upper layers of the soil. The harvest is declining. To improve the health of the soil, it is treated with various disinfectants (the most accessible solution is potassium permanganate), and ammonium nitrate is added during spring plowing , which helps strengthen the plant’s immunity from the appearance of the very first leaves. Physiologically healthy cultures deprive fungi of their “home”; the body rejects foreign microspores.

Ammonium nitrate - formula and composition of fertilizer

This substance is a white powder or granules with a yellowish tint. Granulated ammonium nitrate has the same properties as powder, but decomposes a little more slowly in the soil.

This drug has other names:

  • nitric acid salt;
  • Ammonium nitrate.

Ammonium nitrate formula: NH4NO3

. Some manufacturers add sulfur to its composition, which is also required by cultivated plants for active growth. The percentage of this trace element in ammonium nitrate is up to 13%.

Table:

There are several varieties of this drug, depending on the additional elements included in its composition:

  • Indian saltpeter
    - in addition to active nitrogen, it also contains potassium. As a result, this fertilizer, when applied to the soil, simultaneously promotes the growth of vegetative mass by the plant, and also prepares it for active budding and ripening of fruits.
  • Norwegian
    - it contains carbonate (like lime), magnesium and potassium. During the production process of the drug, its granules are exposed to petroleum products, which break down for a long time in the soil. As a result, nutrients are supplied to the soil in portions over a long period.
  • Ammonium nitrate B
    , which contains nitrogen, sulfur, magnesium, calcium, potassium.
  • Magnesium
    , in this preparation magnesium ions are part of the crystal lattice of the substance.
  • Ammoniated calcium nitrate
    . This fertilizer can be applied to almost all cultivated plants, fruit trees and shrubs. The drug prevents soils from acidifying, maintaining their neutral or slightly acidic reaction.

Types of saltpeter

There are several different types of this fertilizer.

Simple saltpeter

used to simply enrich the soil with nitrogen. This is a worthy replacement for urea.

Potassium nitrate

has potassium as its main substance. Used only in certain periods: the moments of flowering and the beginning of fruit set. It affects the taste of ripened fruits, significantly improving its characteristics.

Calcium nitrate

required to enrich the soil with calcium. When there is a lack of the chemical element calcium, the development of the crop slows down, the root system begins to gradually rot, and the stems grow more and more slowly.

Magnesium

serves as a source of magnesium.

Sodium

is a type of potassium nitrate.

Calcium ammonium nitrate

contains microelements such as magnesium, potassium, calcium. Presented in granular form. They are strong and durable, and therefore can be stored for a long time and can be easily transported to different distances. When particle oil treatment is present, it significantly reduces the risk of increasing soil acidity.

Brand B

created to enrich the soil for seedlings, as well as house plants.

Ammonium nitrate application rate

In the spring, ammonium nitrate in powdered or granular form can be added to the planted seedlings of any vegetable crops.

, 5-10 g of the drug should be used per square area. Typically, fertilizer is applied 12-15 days after transplanting seedlings into open ground, or 18-21 days after sprouts appear.

Before planting root crops in the prepared beds, pour up to 30 g of the drug per square area

. If the soil is severely depleted, then the dose of ammonium nitrate should be increased to 50 g per 1 m2.

For fruit bushes, the dosage of applying nitric acid salt is up to 18 g per 1 m2

. The fertilizer is scattered around the tree trunk after digging.

Fertilizer application rates for various crops of ammonium nitrate - video

To feed fruit trees, 24-28 g of the drug is diluted in a bucket of water and poured into the tree trunk in the spring after flowering.

. After about a month, fruit trees are re-fertilized with this fertilizer.

Important!

After plants or fruit trees and shrubs have been fed with ammonium nitrate solution, they should be watered with plain water so that the root system does not burn.

Feedback on the use of fertilizer

Galina, Suzdal

Ammonium nitrate is a rather aggressive fertilizer, but if you follow all the instructions, it gives a good effect. I start using it in early spring, when the snow has not yet melted. It does not lose its properties as quickly as urea when it reaches the surface.

Valery, Omsk

I don’t like ammonium nitrate because it is not applicable to all crops. And you can’t spray plants with it. Removed ants from the house.

The use of ammonium nitrate in the garden

Ammonium nitrate

– one of the most popular fertilizers among gardeners and gardeners in the spring and early summer, which is used to ensure that cultivated plants actively increase their vegetative mass.
In summer and autumn, nitrogen-containing fertilizers (including ammonium nitrate) should not be applied to the soil.
In this case, plants and trees will only grow green mass, stems and shoots. Shoots and branches on trees and shrubs that grow in mid- and late summer do not have time to become woody before the cold weather begins and simply freeze out in winter.

Below we will describe for which vegetable and garden crops ammonium nitrate is used.

Application of ammonium nitrate - video

Ammonium nitrate for vegetable seedlings

Ammonium nitrate is rarely used to feed vegetable seedlings. Most often, liquid organic fertilizers and urea are applied to seedlings (with an interval of 10-12 days).

But, for example, ammonium nitrate is necessarily used to feed tomato seedlings. For the first time, these seedlings are fertilized with a solution of mullein, and after 12-14 days you can add a solution of nitrate, diluting 15-20 g of the drug in a bucket of water. This amount of solution is used to apply 3 m2 of crops.

Ammonium nitrate for tomatoes

Nitrogen is needed by young tomato bushes so that they actively grow green mass and strengthen the stems

. Ammonium nitrate contains about 34% of this macroelement, so it can be used as the main fertilizer in the spring, as well as as part of a complex fertilizer in combination with potassium salt and superphosphate.

Ammonium nitrate is also added to planting holes (1 tbsp) when planting tomatoes in a permanent place. Also, 5 g of this nitrogen fertilizer is sprinkled on each m2 during the period of active flowering.

The use of ammonium nitrate for cucumbers

Ammonium nitrate is added to the soil before planting cucumber seeds or their seedlings in a permanent place in the garden. It should be buried about 8-10 cm into the soil for spring digging. Many vegetable growers simply scatter this fertilizer around the garden during the period of massive snow melting.

During the period of growth of cucumber vines before flowering, you can water them with a solution of ammonium nitrate, diluting 15-20 g of the drug in a bucket of water.

It is important to know!

However, experts warn that this crop actively accumulates nitrates in its fruits, so ammonium nitrate should be applied under it with great caution and in no case exceed the doses specified in the instructions for use.

Ammonium nitrate for potatoes

Before planting potato tubers in holes, add 1 tbsp. l. Ammonium nitrate. Subsequently, after 18-20 days, the dry preparation should be scattered over the area at the rate of 5 g per square area.

Fertilizing potatoes with ammonium nitrate - video

Fertilizing strawberries with ammonium nitrate

Before planting strawberries in a permanent place, compost or humus is added to the prepared beds at the rate of at least 5 kg per 1 m2. In the first year after planting this berry crop, it is not recommended to apply nitrogen-containing fertilizers, because they provoke rotting of the strawberry bushes.

Starting from the second season in the spring, ammonium nitrate should be added to strawberry beds.

. The application rate of the drug is 100 g per 1 m2 of area. Trenches 10 cm deep are dug along the rows, into which nitrogen fertilizer is poured in an even layer, the furrows are leveled with a rake and watering is carried out.

Next season, strawberries are fertilized with complex fertilizer, which contains per 10 m2:

  • phosphorus – 100 g;
  • potassium salt – 100 g;
  • ammonium nitrate – 110-140 g.

This composition is applied to the beds during the period of green mass appearance, as well as after harvesting ripe fruits.

Instead of dry fertilizer in the spring, you can fertilize with ammonium nitrate solution

. To do this, dilute up to 30 g of fertilizer in a bucket of water and carefully water the bushes strictly at the root.

Ammonium nitrate for root vegetables: beets, carrots, etc.

When preparing beds for planting root crop seeds, ammonium nitrate is applied to the furrows that are made between the rows. This fertilizer is added to them in dry form.

Ammonium nitrate for fruit trees: apple, pear, plum, apricot, peach and others

In the spring, when the snow has completely melted, it is time to feed all fruit trees and shrubs.

. During this period, cultivated plants in the garden need fertilizers containing nitrogen.

Nitrogen nitrate should be applied to the tree trunks of fruit trees several times during the summer.

.

Prepare the solution as follows: dissolve up to 30 g of the drug in a bucket of water. This proportion is the most optimal and saturates the soil with a sufficient amount of nitrogen. Watering with ammonium nitrate is carried out strictly in the tree trunk circles, preventing the drug from getting on the bark and vegetative mass of the trees.

Fruit trees are fertilized at least 3 times per season with an interval of 18-20 days.

Description of fruit tree varieties!
Apricot Northern Triumph Plum Study Apricot Royal Peach Redhaven

Fertilizing berry bushes with ammonium nitrate (raspberries, honeysuckle, currants, blackberries, gooseberries)

You can also apply this preparation to fruit bushes several times a season, but strictly “at the root.”

. For gooseberry and currant bushes up to 3 years old, the rate of application of this fertilizer is up to 30 g per square. During the period of active ripening of berries, the consumption of ammonium nitrate should be up to 50 g.

Spring feeding of these shrubs with ammonium nitrate can be carried out even in the snow.

But it is better to carry it out after the snow has melted, and bury the fertilizer into the soil to a depth of 9-11 cm.

Fertilizing garlic with ammonium nitrate

Garlic, like many other root vegetables, really needs nitrogen, which promotes the active germination of cloves.

Fertilizing garlic in spring using ammonium nitrate - video

Ammonium nitrate is applied to the beds with garlic in the spring at the rate of 1 tbsp. l. drug per square area. Or you can prepare a solution of ammonium nitrate according to the instructions for use (up to 30 g per bucket of water). Fertilizing garlic with ammonium nitrate in the spring is carried out in the snow.

You can also apply this fertilizer under garlic in the fall - before the onset of cold weather.

Ammonium nitrate for flowers

Ammonium nitrate is also actively used in gardening, adding it in the spring in order to stimulate foliage growth.

For perennials, granules of the drug are applied during the snow melting period - in this case, the fertilizer reaches the roots faster along with the melted snow. In this case, additional watering of the plants is not required - due to the large amount of melt water, the flower roots will not be burned by the preparation.

In mid-spring, when the flowers begin to actively grow, it is better to feed them with a solution of ammonium nitrate (up to 2 tablespoons per bucket of water), in this case the nutrients will flow to the roots evenly.

When the first buds appear on flowering plants, fertilizing with ammonium nitrate is stopped, otherwise the vegetative mass of these crops will continue to increase to the detriment of flowering. Because of this, aphids may appear more actively on the bushes.

FUNGICIDES for the GARDEN AND VEGETABLE VEGETABLE!
Bordeaux mixture Fungicide Antracol

Ammonium nitrate for roses

“Queens of flowers” ​​require ammonium nitrate no less than other cultivated plants during the period of active growth. Therefore, this fertilizer with a large amount of nitrogen is applied for the first time at the end of April or beginning of May after the spring sanitary pruning of the bushes has been carried out.

Varieties of beautiful roses!
Rose Gloria Day climbing Rose floribunda climbing Rumba Yellow rose floribunda Arthur Bell
To do this, dilute this drug in a bucket of water (the norm is 1 tbsp.). Other fertilizers should be added to this solution - superphosphate and any potassium salt. Approximately 6 liters of this liquid fertilizer is applied to each plant.

. These complex fertilizers first of all activate the growth of roots, which will serve as an impetus for the start of sap flow.

After 2-3 weeks, similar feeding should be repeated in order to activate the appearance of buds

. After the first flowers begin to appear on the rose bushes, ammonium nitrate is no longer added, otherwise the vegetative mass, including young shoots, will continue to grow, and flowering will be inactive (or buds will not appear at all).

Ammonium nitrate for lawn

After winter, the lawn grass does not look very attractive - some freezes, some dried grass remains, and there is very little fresh greenery. But after a month and a half, young greenery comes from the roots. And all dried and frozen grass should be removed during spring cleaning in the garden.

To activate the growth of green mass, it is recommended to add ammonium nitrate to the lawn.

. The consumption of this granular fertilizer is no more than 40 g per 1 m2. All granules are evenly distributed over the surface of the earth, then abundant watering is carried out.

Important!

You cannot increase the dosage of the drug, otherwise you can burn all the roots of the lawn grass.

The use of ammonium nitrate for indoor plants

Not every indoor plant needs to be fertilized with ammonium nitrate, so in each specific case, before applying this drug, you need to read the literature about what specific fertilizers your flowers need.

This nitrogen fertilizer is best suited for long-growing indoor plants - palm trees, ferns, as well as other ornamental crops, the main advantage of which is foliage

. After all, the main property of nitrogen is the ability to give impetus to the development of the above-ground parts of plants (shoots, foliage).

Usually, all fertilizers for indoor flowers are applied in liquid form, and saltpeter is no exception.

. Usually no more than 2 tbsp is diluted in a bucket of water. l. Saltpeter, and for each plant an amount of liquid fertilizer is applied, proportional to the capacity of the pot or flowerpot.

Foliar feeding with ammonium nitrate

Foliar feeding of any vegetable plants, flowers (including indoor flowers), fruit trees and shrubs is usually not carried out, since the solution of this drug is quite concentrated and causes burns to the leaf blades

. Because of this, plants get sick for a long time and often die.

Some summer residents still carry out leaf feeding of some cultivated plants, but the amount of ammonium nitrate in the solution should not be more than 0.25 g per 1 liter of water. In a private household, it is extremely difficult to measure such an amount of the drug.

Nitrogen fertilizers for the garden - video

Fertilizing with ammonium nitrate

Fertilizing of fruit trees, flowers, roses, lawns and indoor flowers is also carried out carefully, avoiding exceeding the dosage of this drug. Fruit trees and shrubs have the ability to accumulate nitrates in ripening fruits, which negatively affects human health.

The best fertilizers for the vegetable garden!
Epin Extra Potassium Nitrate Superphosphate Potassium Monophosphate
The use of ammonium nitrate in gardening allows you to increase the volume of vegetative mass, improves flowering and fruiting, but strict adherence to the rate of application of the drug to the soil is required.

Manufacturing process

There are several methods for producing this substance.

On an industrial scale.

On an industrial scale, anhydrous ammonia and concentrated nitric acid are used. There are several stages.

First stage.

As a result of the reaction, a large amount of thermal energy is released.

Second phase.

Such a reaction should only occur under special conditions, subject to safety precautions.

Third stage.

After a solution has formed, excess water is evaporated, reaching the state of a melt, which is then granulated in special devices, dried, cooled and coated with compounds to prevent caking. The color of the granules itself can be either colorless or white.

Fourth stage.

During the production stage, additional elements such as potassium, calcium or magnesium are usually added to ammonium nitrate. This is necessary to obtain different varieties.

Questions from gardeners and gardeners

Below are the most frequently asked questions from readers about this nitrogen fertilizer, along with their answers.

Why is ammonium nitrate needed?

Ammonium nitrate is needed to enrich the soil with nitrogen, which is needed by all cultivated plants in the garden to increase vegetative mass.

What is the chemical formula of ammonium nitrate?

The chemical formula of this drug is NH4NO3.

How much nitrogen is in ammonium nitrate?

This drug contains approximately 34% nitrogen.

Are urea and ammonium nitrate the same thing?

Urea (or carbamide) and ammonium nitrate are completely different fertilizers, the main advantage of which is their high nitrogen content. And if the first preparation contains up to 46% nitrogen, then ammonium nitrate contains only up to 34% of this mineral element.

Urea can be used to apply root and leaf fertilizers, while ammonium nitrate is applied only to the soil.

Urea takes longer to be absorbed by plants, and ammonium nitrate has the ability to be absorbed more quickly by the root system of plants.

Description of urea and ammonium nitrate - pros and cons

What is the price of ammonium nitrate?

The cost of 1 kg of ammonium nitrate is about 13-14 rubles per 1 kg.

What is the composition of ammonium nitrate?

This chemical contains nitrogen, hydrogen, and oxygen. Sulfur, magnesium, potassium, and calcium are often added to ammonium nitrate.

How many grams of ammonium nitrate are in a tablespoon?

One tablespoon contains approximately 13 g of this drug.

How to replace ammonium nitrate for fertilizing?

Ammonium nitrate can be replaced with any other drug containing approximately the same amount of nitrogen in its composition.

How much ammonium nitrate is in a matchbox?

A matchbox can contain no more than 20 g of ammonium nitrate.

Ammonium nitrate or azofoska - which is better?

It is impossible to say unequivocally that one of these fertilizers is better or worse. It’s just that ammonium nitrate contains only easily digestible nitrogen, so it is used only in the spring and early summer.

And azofoska contains all the main components necessary for plants to grow and develop fruits - potassium, phosphorus and nitrogen. Therefore, this fertilizer can be used for application to garden and vegetable crops throughout the spring and summer season.

Where to buy ammonium nitrate?

You can purchase ammonium nitrate in any specialized store, or order it online.

Urea (urea) or ammonium nitrate - which is better?

Urea contains 2 times more digestible nitrogen than ammonium nitrate, so the nutritional properties of 2 kg of urea are equal to 6 kg of ammonium nitrate.

In addition, urea can be used for foliar feeding when plants require urgent nitrogen application, otherwise they may die.

Which is better ammonium nitrate or urea - video

What brands of ammonium nitrate are there?

There are only two brands of this fertilizer: A and B.

What is the hazard class of ammonium nitrate?

This drug is classified as hazard class 5; it does not ignite in direct contact with fire, but can explode - it decomposes at high ambient temperatures and releases oxygen.

Price issue

Ammonium nitrate is a very economically advantageous agrochemical. Its price is about 20-25 rubles per kg. If we take into account that the rate of application of this mineral fertilizer is, on average, about 10-20 g/sq. m., then for one hundred square meters (100 sq. m.), it is necessary to spend only 1 kg of fertilizer.
Even taking into account the fact that the use of ammonium nitrate is not very rational without other mineral fertilizers, fertilizing with it is very profitable.

You can buy ammonium nitrate either in bulk or in packaged form. Very often in stores selling products for gardeners, you can find its varieties with various additives. They have a narrower application, but at the same time, they solve specific problems better than the main fertilizer with a wide range of uses.

Ammonium nitrate - reviews from gardeners and gardeners

Natalya, 55 years old, Kazan: I use this fertilizer to feed my fruit trees in spring and summer. I also apply ammonium nitrate to gooseberries, currants and strawberries, but only in the spring. I buy small packages of this drug and usually use them in one season so as not to leave them for the next year.

Olga, 49 years old, Volgograd: I use ammonium nitrate to feed most vegetable crops and root crops during the spring. As a result, all my plants are green and strong. I am also pleased with the cheap price of this fertilizer.

You can use ammonium nitrate in your garden and garden throughout the spring.

The undeniable advantage of the drug is that it can even be scattered on the snow, and it will be absorbed immediately into the soil, and will not flow away with melt water. The low cost and optimal amount of easily digestible nitrogen in this fertilizer are also advantages of ammonium nitrate.

Advantages and disadvantages

Ammonium nitrate is used as a growth accelerator for flowers, trees and shrubs. The fertilizer is also used for fruit and vegetable crops.

In addition, it helps to increase yield and reduces exposure to negative factors - parasites, fungal infections of leaves and unfavorable weather conditions.

It is widely used not only in green farming, but also for indoor flowers: in combination with phosphate, they nourish the soil well. Ideal for feeding palm trees and slow-growing ornamental potted plants.

What it is?

Ammonium nitrate is a mineral fertilizer based on nitrogen (26% to 34.4%) and sulfur (3-14%). Nitrate has other names: ammonium nitric, ammonium nitrate, ammonium salt of nitric acid.

Fertilizers with a sulfur component are especially well absorbed by plants. Sulfur in this tandem acts as a corrector , because in itself it is not a nutritional element for garden crops.

Formula: NH4+. Chemical composition: nitrates, metals, ammonium with a positive ion charge.

Composition of ammonium nitrate

Fertilizer belongs to the group of preparations with a high nitrogen content. From a chemical point of view, it is ammonium nitrate. Ammonium nitrate granules consist of 34% nitrogen. The chemical composition of the drug does not allow it to be stored together with such materials as:

  • Peat;
  • Sawdust;
  • Lime;
  • Organic substances.

Their presence can provoke spontaneous combustion. Nitrate can be mixed with potassium and phosphate fertilizers, but mixing can only be done before adding the preparations to the soil.

Receipt

Ammonium nitrate is obtained by neutralizing nitric acid with ammonia gas:

HNO3 + NH3 (gas) → NH4NO3 + 144.9 kJ

The resulting solution of ammonium nitrate is evaporated, subjected to crystallization and finally dried. Various impurities are added to the resulting substance to improve its physical and chemical properties.

Physical and chemical properties

Ammonium nitrate (without impurities)

– a white crystalline, very hygroscopic substance, in the open air it becomes damp and cakes. Depending on temperature conditions, there are five crystalline modifications that can transform into each other only when the ambient temperature changes.

The fourth and fifth modifications are of practical importance, existing within the following limits:

  • IV – from +32.2 to –16.9°C;
  • V – below –16.9°C. [7]

When transitioning from one modification to another, the substance recrystallizes with a change in volume, and the substance becomes highly compacted. [9]

Density of modification IV is 1.725 g/cm3.

Ammonium nitrate dissolves well in water and other substances:

  • Solubility in water: at 0°C – 119 g per 100 g,
  • at +25°C – 212 g per 100 g,
  • at +50°C – 346 g per 100 g.
  • Solubility in liquid NH3 at +25°C – 391 g per 100 g.
  • Dissolves ammonium nitrate in methanol, ethanol, pyridine.
  • At 200–270°C it decomposes into nitrogen oxide and water, releasing heat. Above 270°C or when subjected to shock, decomposition is accompanied by an explosion. [7]
  • Ammonium nitrate (fertilizer)

    - a granular substance with much less hygroscopicity. Granule size is 1–4 mm. The fertilizer contains various additives to reduce caking. Condensing substances can be finely ground phosphate rock, gypsum, kaolinite, magnesium nitrate, etc. These additives give the fertilizer a yellowish tint. Fixin, administered as an additive, gives it a reddish color. [9]

    Ammonium nitrate (fertilizer) meets the following requirements:

    • nitrogen content in dry matter – not less than 34%;
    • water content – ​​no more than 0.2–0.3%;
    • acidity of a 10% aqueous solution – 4–5%;
    • statistical strength of granules – 5–7 N/granule;
    • friability – not less than 100%. [2]

    Ammonium nitrate (fertilizer) is an oxidizing agent. Fire hazardous. At a temperature of 210 °C and interaction with sulfur, sulfur pyrites, acids, superphosphate, bleach and powdered metals, it decomposes, releasing toxic oxides of nitrogen and oxygen.

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